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They first got to know each other on the set of Mr. and Mrs. Smith. Brad Pitt, who was still married to Jennifer Aniston at the time, was then introduced to Angelina Jolie’s toddler son Maddox.

At the time, sources on the film said that Jolie, now 47, would show up at Pitt’s trailer and tell him: ‘Maddox would like to say "Hi."' Pitt, now 58, was enchanted – by the boy and his mother.